By Boresi and Schmidt
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Extra info for Advanced Mechanics of Materials 6th edition Solution Manual
Estimation of Heat of Reaction from Bond Energies The determination of the heat of reaction depends on the availability of the heats of formation. In the event that they are not available, rough estimates of their values can be obtained from the bond energies between the atomic constituents of the reactant and product molecules (McMillen & Golden 1982). The methodology is based on the concept that the energy needed to break a particular type of bond between two atoms is approximately the same regardless of the molecule in which the bond is present.
15) or where λ is a parameter indicating the progress in reaction. Substituting Eq. 15) into Eq. 12), we have N µ¯ i (νi − νi ) dλ = 0. 17) i=1 which shows that at equilibrium the sum of the chemical potentials of all the reactants is equal to that of the products. 4. Phase Equilibrium The equilibrium criterion Eq. 17) derived above can be readily used to describe phase equilibrium. Consider for example a simple transition from phase to phase g without molecular decomposition, M → Mg . 2. Chemical Equilibrium July 19, 2006 19 and νg = 1, where the subscripts and g can designate any two phases.
With the convenience of modern computational capability, such a simplification, with the collateral inaccuracy, is however neither necessary nor worthwhile. We shall now discuss the dependence of Tad on the fuel concentration, fuel type, and pressure of the fuel–air mixture, obtained from computer solutions.
Advanced Mechanics of Materials 6th edition Solution Manual by Boresi and Schmidt