Oleg I. Kolodiazhnyi's Asymmetric synthesis in organophosphorus chemistry: PDF

By Oleg I. Kolodiazhnyi

ISBN-10: 3527341501

ISBN-13: 9783527341504

ISBN-10: 352734151X

ISBN-13: 9783527341511

ISBN-10: 3527341528

ISBN-13: 9783527341528

ISBN-10: 3527341536

ISBN-13: 9783527341535

ISBN-10: 3527341544

ISBN-13: 9783527341542

Authored via one of many prime specialists within the box, this can be the single accomplished evaluate of chiral organophosphorus compounds, from uneven synthesis to catalysis and pharmacological applications.
As such, this specific reference covers the chemical history in addition to spectroscopical research of phosphorus compounds, and punctiliously describes all of the quite a few artificial recommendations for those elements. Metal-, organo- and biocatalyzed reactions for the advent of phosphorus are defined as are uneven oxidation and aid equipment for the guidance of all attainable oxidation states of phosphorus. The textual content additionally comprises commercial functions for those compounds.
Of specific curiosity to chemists operating within the box of uneven synthesis, in addition to to the pharmaceutical a result of expanding variety of phosphorous-containing medicines

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Additional resources for Asymmetric synthesis in organophosphorus chemistry: synthetic methods, catalysis, and applications

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The CD method is successfully used for determination of the AC of hydroxyphosphonates [106, 110, 111]. CD involves circularly polarized light. Left-hand circular (LHC) and right-hand circular (RHC) polarized light represent two possible spin angular momentum states for a photon, and so CD is also referred to as dichroism for spin angular momentum. It is exhibited in the absorption bands of optically active chiral molecules. For example, Wynberg and co-workers [110] used the CD spectra to determine the AC of a number of chiral α-hydroxy phosphonates.

Angew. Chem. Int. Ed. , 29 (9), 939–957. , and Shum, W. (1990) A convenient gas chromatographic method for the optical purity determination of chiral epoxy alcohols. , 31, 4389–4390. P. (1987) Gas chromatography 81 82 83 84 85 86 87 88 89 90 91 92 93 of organophosphorus compounds on chiral stationary phases. Int. J. Environ. Anal. , 30 (1-2), 15–28. , and Keglevich, G. (2014) Resolution of 1-n-butyl-3-methyl-3-phospholene 1-oxide with TADDOL derivatives and calcium salts of O,O’-dibenzoyl-(2R,3R)- or O,O’-di-p-toluoyl-(2R,3R)-tartaric acid.

Asymmetrische synthesen mit ketenen, 1 Alkaloid-katalysierte asymmetrische Synthesen von α−Phenyl-propionsaureestern. Justus Liebigs Ann. , 634 (1), 9–22. J. (1951) Determination of the absolute configuration of optically active compounds by means of X-rays. Nature, 168 (4268), 271–272. A. S. (1973) Nuclear magnetic resonance enantiomer reagents. alpha, trifluoromethylphenylacetate (MTPA) esters. J. Am. Chem. , 95 (2), 512–519. M. H. (1972) Shift reagents in NMR spectroscopy. Nature, 240, 385–390.

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Asymmetric synthesis in organophosphorus chemistry: synthetic methods, catalysis, and applications by Oleg I. Kolodiazhnyi


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