Download PDF by Ari M. P. Koskinen: Asymmetric synthesis of natural products

By Ari M. P. Koskinen

ISBN-10: 1118347323

ISBN-13: 9781118347324

ISBN-10: 1119976685

ISBN-13: 9781119976684

ISBN-10: 1119976693

ISBN-13: 9781119976691

ISBN-10: 1280775718

ISBN-13: 9781280775710

Asymmetric Synthesis of common Products, 2d variation introduces scholars to this swiftly growing to be box of natural chemistry. The preliminary chapters current the principles of uneven synthesis, together with the idea and purposes of person uneven reactions. this is often through chapters on all the significant person sessions of ordinary items; their buildings, biosynthesis and interrelationships in addition to examples of uneven syntheses and the sensible price of those compounds. common product periods coated comprise carbohydrates, amino acids, peptides, proteins, nucleosides, nucleotides, nucleic acids, polyketides, isoprenoids, shikamic acid derivatives and alkaloids.

For this moment variation the textual content has been completely up-to-date and multiplied, and contains new discussions and examples protecting atom and redox economies, functional features and environmental information. Organocatalysis has emerged thoroughly within the final ten years, and has been totally built-in into this new edition.

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Am. Chem. , 122, 2657. , and Marquarding, D. (1967) Justus Liebigs Ann. , 7091. (a) Dömling, A. (2006) Chem. , 106, 17; (b) Dömling, A. and Ugi, I. (2000) Angew. Chem. Int. , 39, 3168. (a) Kunz, H. and Pfrengle, W. (1988) J. Am. Chem. , 110, 651; (b) Kunz, H. and Pfrengle, W. (1988) Tetrahedron, 44, 5487. , and Sager, W. , 30, 4109. Zech, G. and Kunz, H. (2004) Chem. Eur. , 10, 4136. , and Pellicciari, R. (2004) Farmaco, 59, 93. , and Urban, R. (1982) Chemistry and Biochemistry of Amino Acids, Peptides and Proteins, vol.

The glycopyranoside-based diastereoselective 1,4-additions were further developed by the Tadano group using other hexopyranosides, such as α-d-mannoand α-d-galactopyranosides. 10 shows representative examples for the d-mannopyranose-based approach [18]. Thus, two 3-O-crotylated-α-dmannopyranosides, 50 and 52, were synthesized from known methyl 4,6-O-benzyl-α-d-mannopyranoside. Selective O-benzylation of the 4,6-di-O-benzyl derivative provided 49, which was acylated with crotonic anhydride to provide the 3-O-crotonyl ester 50.

Perkin Trans. 1, 2139. Goebel, M. and Ugi, I. (1991) Synthesis, 1095. , and Ugi, I. (1995) Angew. Chem. Int. Ed. , 34, 1104. (a) Micheel, F. and Klemer, A. (1961) Adv. Carbohydr. , 16, 95; (b) Pfleiderer, W. and Bühler, E. (1966) Chem. , 99, 3022. , and Ugi, I. (2002) Tetrahedron, 58, 6127. L. L. (1962) J. Org. , 27, 3896. (a) Birkofer, L. and Ritter, A. (1965) Angew. Chem. Int. Ed. , and Friedmann, M. (1974) Chem. , and Gyorgydeak, Z. (1999) Carbohydr. , 318, 91. F. and Ugi, I. (2001) Can. J. , 79, 1934.

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