New PDF release: Bioinspired Catalysis: Metal-Sulfur Complexes

By Wolfgang Weigand, Philippe Schollhammer

ISBN-10: 3527333088

ISBN-13: 9783527333080

This publication offers an outline of bioinspired metal-sulfur catalysis via overlaying buildings, actions and version complexes of enzymes displaying steel sulphur moieties of their lively heart.

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Download PDF by Wolfgang Weigand, Philippe Schollhammer: Bioinspired Catalysis: Metal-Sulfur Complexes

This booklet offers an outline of bioinspired metal-sulfur catalysis via masking constructions, actions and version complexes of enzymes displaying steel sulphur moieties of their lively middle.

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Subsequently, the isc (iron–sulfur cluster) and suf (sulfur mobilization) operons were discovered [20, 21], first in prokaryotes and later in yeast and mammals, underscoring their ubiquity [17, 18]. These two systems seem to be specific: in Escherichia coli, the isc operon is responsible for the assembly machinery of Fe–S clusters under normal growth conditions, whereas the suf operon appears to function when bacteria are exposed to stress [13]. Homologs of the suf operon are also found in plastids and cyanobacteria [26, 27].

17 18 1 From Chemical Invariance to Genetic Variability 36. , and 37. 38. 39. 40. 41. 42. 43. 44. 45. C. (2006) Maturation of hydrogenases. Adv. Microb. , 51, 1–71. , and Lenz, O. (2011) Probing the origin of the metabolic precursor of the CO ligand in the catalytic center of [NiFe] hydrogenase. J. Biol. , 286, 44937–44944. G. (1979) Reactions of iron monosulfide solids with aqueous hydrogen sulfide up to 160 ∘ C. J. Inorg. Nucl. , 41, 1683–1687. O. (1990) Pyrite formation linked with hydrogen evolution under anaerobic conditions.

Science, 289, 1337–1340. , and Albrecht, P. (2010) Elucidation of an iterative process of carbon-carbon bond References 56. 57. 58. 59. 60. 61. formation of prebiotic significance. Astrobiology, 10, 973–988. P. and Fritz, M. (1993) Emergence of CNH and cyano complex based organometallic chemistry. Chem. , 93, 1243–1280. Huber, C. and Wächtershäuser, G. (1998) Peptides by activation of amino acids on (Fe,Ni)S surfaces: implications for the origin of life. Science, 281, 670–672. , and Wächtershäuser, G.

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Bioinspired Catalysis: Metal-Sulfur Complexes by Wolfgang Weigand, Philippe Schollhammer


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